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Designation:D7220 ? 12 (Reapproved 2017)
Standard Test Method for
Sulfur in Automotive, Heating, and Jet Fuels by Monochromatic Energy Dispersive X-ray Fluorescence Spectrometry
用單色能量色散x射線熒光光譜法測定汽車燃料、加熱燃料和噴氣燃料中硫的標準試驗方法
1.Scope
1.1 This test method specifies an energy-dispersive X-ray fluorescence (EDXRF) method for the determination of total sulfur in automotive, No. 2 heating, and jet fuels with a concentration range of 3 mg ?kg to 942 mg ?kg.
1.1.1 The pooled limit of quantitation of this test method as obtained by statistical analysis of inter laboratory test results is 3 mg ?kg sulfur.
1.1.2 This test method is applicable to gasoline, oxygen enriched gasoline (RFG), diesel, diesel/biodiesel blends con- taining up to twenty volume percent biodiesel, kerosene, jet fuel, jet fuel/biodiesel blends containing up to five volume percent biodiesel and No. 2 home heating oil.
1. 范圍
1.1 本試驗方法規定了用于測定3 mg/kg至942 mg/kg濃度范圍內汽車燃料、2號加熱燃料和噴氣燃料中總硫的能量色散X射線熒光（EDXRF）法。
1.1.1 通過實驗室間試驗結果的統計分析獲得的本試驗方法的總定量限為3 mg/kg硫。
1.1.2 本試驗方法適用于汽油、富氧汽油（RFG）、柴油、含20%生物柴油的柴油/生物柴油混合物、煤油、噴氣燃料、含5%生物柴油的噴氣燃料/生物柴油混合物和2號家用取暖油。
15.2 The precision of the test method is as follows:
15.2.1 Repeatability—The difference between successive test results obtained by the same operator with the same apparatus under constant operation conditions on identical test material would, in the long run, in the normal and correct operation of the test method, exceed the value:
15.2 試驗方法的精度如下：
15.2.1 重復性—從長期來看，在試驗方法的正常和正確
操作中，同一操作員在相同試驗材料上使用相同儀器在恒定操作條件下獲得的連續試驗結果之間的差值，20個結果中只有1個結果，將超過以下值（見表3）：
0.6430·X0.504mg/kg (5)
where:
X = the mean sulfur content of two results between 3 and 942 mg/kg, only in one case in twenty. (See Table 3.)
15.2.2 Reproducibility—The difference between two single and independent results obtained by different operators work- ing in different laboratories on identical test material would, in the long run, in the normal and correct operation of the test method, exceed the value:
那里：
X = 在3到942 mg/kg 之間的兩個結果的平均硫含量。
15.2.2 再現性—從長期來看，在試驗方法的正常和正確操作中，在不同實驗室對同一試驗材料進行操作的不同操作員獲得的兩個單獨和獨立結果之間的差值，20個結果中只有1個結果，將超過以下值（見表4）：
1.1121·X0.504mg/kg (6)
where:
X = the mean sulfur content of two results between 3 and 942 mg/kg, only in one case in twenty. (See Table 4.)
式中：
X = 在3到942 mg/kg之間的兩個結果的平均硫含量。
TABLE 3，4 Precision Values, All Sample Types
表3，4 精度值（所有樣品類型）
|
S,mg/kg |
Repeatability r,mg/kg Eq 5 values |
Reproducibility R, mg/kg Eq 6 values |
|
3 |
1.1 |
1.9 |
|
5 |
1.4 |
2.5 |
|
10 |
2.1 |
3.5 |
|
25 |
3.3 |
5.6 |
|
50 |
4.6 |
8.0 |
|
100 |
6.5 |
11.3 |
|
250 |
10.4 |
18 |
|
500 |
14.7 |
25.5 |
|
942 |
20.3 |
35.1 |
.
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